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Chiral halogen and chalcogen bonding receptors for discrimination of stereo- and geometric dicarboxylate isomers in aqueous media†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-10 00:00:00 , DOI: 10.1039/c8cc06400h
Jason Y. C. Lim 1, 2, 3, 4, 5 , Igor Marques 2, 6, 7, 8, 9 , Vítor Félix 2, 6, 7, 8, 9 , Paul D. Beer 1, 2, 3, 4, 5
Affiliation  

Novel chiral halogen and chalcogen bonding receptors exhibit different selectivities for stereo- and geometric dicarboxylate isomers compared to a hydrogen bonding analogue. The unique geometric and electronic properties of the chalcogen bonding receptor facilitate the diagnostic fluorescence sensing of geometric dicarboxylate isomer guest species.

中文翻译:

手性卤素和硫族元素键合受体,可区分水性介质中的立体和几何二羧酸酯异构体

与氢键类似物相比,新型手性卤素和硫属元素键合受体对立体和几何二羧酸酯异构体具有不同的选择性。硫属元素结合受体的独特几何和电子特性有助于几何二羧酸酯异构体客体物种的诊断荧光感测。
更新日期:2018-09-10
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