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Cu-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2018-09-07 , DOI: 10.1016/j.jfluchem.2018.09.001
Wei Zhang , Jin-Hong Lin , Ji-Chang Xiao

Although CF3SO2Cl is an efficient chlorotrifluoromethylation reagent, an expensive transition metal complex usually has to be used. We found that CuCl2-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl occurred smoothly under mild conditions. A wide substrate scope and good functional group compatibility were observed.



中文翻译:

铜与CF 3 SO 2 Cl催化的烯烃的氯三氟甲基化

尽管CF 3 SO 2 Cl是有效的氯三氟甲基化试剂,但通常必须使用昂贵的过渡金属配合物。我们发现,在温和条件下,CuCl 2催化的带有CF 3 SO 2 Cl的烯烃的氯三氟甲基化反应顺利进行。观察到广泛的底物范围和良好的官能团相容性。

更新日期:2018-09-07
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