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Nitrogen-free commercial carbon cloth with rich defects for electrocatalytic ammonia synthesis under ambient conditions†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-07 00:00:00 , DOI: 10.1039/c8cc06000b
Wenyi Li 1, 2, 3, 4, 5 , Tianxing Wu 1, 2, 3, 4, 5 , Shengbo Zhang 1, 2, 3, 4, 5 , Yanyan Liu 1, 2, 3, 4, 5 , Cuijiao Zhao 1, 2, 3, 4, 5 , Guoqiang Liu 1, 2, 3, 4, 5 , Guozhong Wang 6, 7, 8 , Haimin Zhang 1, 2, 3, 4, 5 , Huijun Zhao 1, 2, 3, 4, 5
Affiliation  

Nitrogen-free commercial carbon cloth treated at 450 °C in air possesses abundant defects, exhibiting superior electrocatalytic activity for the nitrogen reduction reaction (NRR) with an NH3 yield of 2.59 × 10−10 mol cm−2 s−1 and a Faradaic efficiency of 6.92% at −0.3 V (vs. RHE) in 0.1 M Na2SO4 + 0.02 M H2SO4.

中文翻译:

无氮商品碳布,具有丰富的缺陷,可在环境条件下进行电催化氨合成

在空气中经过450°C处理的无氮商品碳布具有丰富的缺陷,对氮还原反应(NRR)表现出优异的电催化活性,NH 3产率为2.59×10 -10 mol cm -2 s -1和法拉第在0.1 M Na 2 SO 4 + 0.02 MH 2 SO 4中,在−0.3 V时的效率(相对于RHE)为6.92%。
更新日期:2018-09-07
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