Acidic Hydrothermal Dehydration of d-Glucose into Humins: Identification and Characterization of Intermediates,ACS Sustainable Chemistry & Engineering

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Acidic Hydrothermal Dehydration of d-Glucose into Humins: Identification and Characterization of Intermediates
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-09-06 00:00:00 , DOI: 10.1021/acssuschemeng.8b03479
Victor Maruani ₁ , Stacy Narayanin-Richenapin ₁ , Eric Framery ₁ , Bruno Andrioletti ₁

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The acidic hydrothermal dehydration of d-glucose into humins was studied. In addition to the well-known intermediates such as 5-hydroxymethylfurfural, which have been identified during the decomposition of d-glucose into humins, water-soluble oligomers of d-glucose (WSO) were identified. After isolation and characterization, the role of the WSO in the formation of humins was investigated. On this basis, we were able to propose a slight modification of the commonly admitted humins structure.

中文翻译：

d-葡萄糖的酸性水热脱水成腐殖质：中间体的鉴定与表征

研究了d-葡萄糖的酸性水热脱水为腐殖质。除了公知的中间体如5-羟甲基，已分解过程中被识别d葡萄糖进入腐黑物，水溶性低聚物d -葡萄糖（WSO）进行了鉴定。分离和鉴定后，研究了WSO在腐殖质形成中的作用。在此基础上，我们能够对公认的人类结构进行稍微的修改。

更新日期：2018-09-06

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