A Molecular Figure of Eight: Synthesis and Characterization,ChemistrySelect

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A Molecular Figure of Eight: Synthesis and Characterization
ChemistrySelect ( IF 1.9 ) Pub Date : 2018-09-06 , DOI: 10.1002/slct.201801982
Sidheswari Prusty _{1,

2} , Mana Bhanjan Podh _{1,

2} , Chandra Shekhar Purohit _{1,

2}

Affiliation

Proving different structure of topologically similar elements are difficult without their molecular structure. In this work, we report the synthesis of molecular figure of eight, with Co(III) template using click chemistry for ring closing. However, this reaction can yield both [2]catenane and figure of eight complexes. In order to prove the conformation, we synthesize an analogous [2]catenane Co(III) complex exclusively, using a different strategy. Both the compounds are characterized by NMR spectroscopy and HPLC.

中文翻译：

分子八图：合成与表征

没有它们的分子结构，很难证明拓扑相似元素的不同结构。在这项工作中，我们报告了使用单击化学进行闭环的Co（III）模板合成八分子图的过程。但是，该反应既可以生成[2]环烷，也可以生成八种配合物。为了证明其构象，我们使用不同的策略专门合成了类似的[2]环戊烷Co（III）配合物。两种化合物均通过NMR光谱和HPLC表征。

更新日期：2018-09-06

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