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Islanding of EuVO4 on high-dispersed fluorine doped few layered graphene sheets for efficient photocatalytic mineralization of phenolic compounds and bacterial disinfection
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.5 ) Pub Date : 2018-09-06 , DOI: 10.1016/j.jtice.2018.08.034
Pooja Shandilya , Divya Mittal , Mahesh Soni , Pankaj Raizada , Ji-Ho Lim , Dae Yong Jeong , Ram Prakash Dewedi , Adesh K. Saini , Pardeep Singh

In present work, EuVO4 (EV) nanoparticles were dispersed over fluorine doped graphene sheets (FG24) to synthesize EV/FG24 nanocomposite. Few layered fluorine doped graphene sheets were prepared by sonochemical exfoliation method using NaF as fluorine source. FG24 and EV/FG24 composites were successfully characterized by FESEM, TEM, RAMAN, XRD, TGA, XPS, BET isotherm, FTIR, photoluminescence and UV–visible spectral techniques. AFM and RAMAN analysis confirmed the formation of fluorine doped graphene sheets. The high dispersion of EV/FG24 in water was ascertained by zeta potential measurement and Tyndall scattering experiment. The photocatalytic activity of EV/FG24 was tested for the degradation of phenolic compounds and bacterial disinfection under visible light. As compared to conventional slurry photocatalytic system, no magnetic stirring was used during degradation experiments. The photodegradation rate was substantially influenced by adsorption of 2, 4-dinitrophenol (DNP) and phenol onto EV/FG24. The DNP and phenol were completely mineralized in 10 h. The selected bacteria were inactivated by EV/FG24 in 3 h. The effect of various radical scavengers revealed the pivotal role of hydroxyl radicals during disinfection mechanism. EV/FG24 exhibited significant recycle efficiency during photocatalytic process. EV/FG24 was used as a stable photocatalyst to depollute contaminated water.



中文翻译:

EuVO 4在高分散氟掺杂的几层石墨烯片上的孤岛化,用于酚化合物的有效光催化矿化和细菌消毒

在目前的工作中,EuVO 4(EV)纳米颗粒分散在氟掺杂的石墨烯片(FG24)上以合成EV / FG24纳米复合材料。使用NaF作为氟源,通过声化学剥离法制备很少层的掺杂氟的石墨烯片。通过FESEM,TEM,RAMAN,XRD,TGA,XPS,BET等温线,FTIR,光致发光和紫外可见光谱技术成功表征了FG24和EV / FG24复合材料。原子力显微镜和拉曼分析证实了氟掺杂石墨烯片的形成。EV / FG24在水中的高度分散是通过zeta电势测量和Tyndall散射实验确定的。测试了EV / FG24的光催化活性对酚类化合物的降解和可见光下细菌的消毒作用。与传统的浆料光催化系统相比,在降解实验中不使用磁力搅拌。2,4-二硝基苯酚(DNP)和苯酚在EV / FG24上的吸附会大大影响光降解速率。DNP和苯酚在10小时内完全矿化。选定的细菌在3小时内被EV / FG24灭活。各种自由基清除剂的作用揭示了在消毒机理中羟基自由基的关键作用。EV / FG24在光催化过程中显示出显着的回收效率。EV / FG24用作稳定的光催化剂,对污染的水进行去污染。各种自由基清除剂的作用揭示了在消毒机理中羟基自由基的关键作用。EV / FG24在光催化过程中显示出显着的回收效率。EV / FG24用作稳定的光催化剂,对污染的水进行去污染。各种自由基清除剂的作用揭示了在消毒机理中羟基自由基的关键作用。EV / FG24在光催化过程中显示出显着的回收效率。EV / FG24用作稳定的光催化剂,对污染的水进行去污染。

更新日期:2018-09-06
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