Synthesis of multifunctional homopolymers via sequential post-polymerization reactions,Polymer Chemistry

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Synthesis of multifunctional homopolymers via sequential post-polymerization reactions
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-09-04 00:00:00 , DOI: 10.1039/c8py01055b
Tomohiro Kubo _{1,

2,

3,

4,

5} , Charles P. Easterling _{1,

2,

3,

4,

5} , Rebecca A. Olson _{1,

2,

3,

4,

5} , Brent S. Sumerlin _{1,

2,

3,

4,

5}

Affiliation

Multifunctional homopolymers, homopolymers with multiple pendent functionalities, can offer unparalleled properties not possible with traditional polymers. Preparation of multifunctional homopolymers has been a challenge, but one promising approach involves sequential and selective post-polymerization modification of macromolecular precursors. Approaches considered thus far include the use of polymers that contain monomer units with masked reaction sites for successive functionalization or the use of orthogonal or chemoselective reactions. In this mini-review, we highlight recent developments in synthesis of multifunctional homopolymers via these routes and offer insight into the promise and utility of the resulting macromolecules for materials applications.

中文翻译：

通过顺序的后聚合反应合成多功能均聚物

多功能均聚物，具有多种侧基官能团的均聚物，可提供传统聚合物无法提供的无与伦比的性能。多功能均聚物的制备一直是一个挑战，但是一种有前途的方法涉及大分子前体的顺序和选择性的聚合后改性。迄今为止考虑的方法包括使用包含具有掩蔽的反应位点的单体单元的聚合物以进行连续官能化，或者使用正交或化学选择性反应。在本小型审查中，我们重点介绍了通过这些途径合成多功能均聚物的最新进展，并深入了解了所得大分子材料在材料应用中的前景和实用性。

更新日期：2018-09-04

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