High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(ii) based on hybrid compounds†,Inorganic Chemistry Frontiers

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High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(ii) based on hybrid compounds†
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2018-09-03 00:00:00 , DOI: 10.1039/c8qi00793d
Yan-Li Wei _{1,

2,

3,

4,

5} , Jing Jing _{1,

2,

3,

4,

5} , Chao Shi _{5,

6,

7,

8} , Heng-Yun Ye _{5,

6,

7,

8} , Zhong-Xia Wang _{1,

2,

3,

4,

5} , Yi Zhang _{1,

2,

3,

4,

5}

Affiliation

Two novel tetrahedral manganese(II) complexes, (N-methylpiperidinium)MnCl₄ (1) and (N-methylpyrrolidinium)MnCl₄ (2), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37% and 2 emits unusual red emission at 611 nm.

中文翻译：

基于杂化化合物的四面体锰（ii）的高量子产率和不寻常的光致发光行为†

通过有机阳离子调制合成了两种新颖的四面体锰（II）配合物（N-甲基哌啶）MnCl ₄（1）和（N-甲基吡咯烷鎓）MnCl ₄（2）。化合物1表现出显着的绿色发光，具有79.37％的高量子产率，化合物2在611 nm处发射不寻常的红色发射。

更新日期：2018-09-03

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