Heterogeneous catalytic water oxidation controlled by coordination geometries of copper(ii) centers with thiolato donors†,Chemical Communications

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Heterogeneous catalytic water oxidation controlled by coordination geometries of copper(ii) centers with thiolato donors†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-09-03 00:00:00 , DOI: 10.1039/c8cc06238b
Naoto Kuwamura _{1,

2,

3,

4,

5} , Yoshinari Kurioka _{1,

2,

3,

4,

5} , Nobuto Yoshinari _{1,

2,

3,

4,

5} , Takumi Konno _{1,

2,

3,

4,

5}

Affiliation

Treatment of a penicillaminato platinum(II) metalloligand with Cu²⁺ gave an S-bridged Pt^II₂Cu^II₂ complex, which reacted with Zn²⁺ to produce 1D and 3D (Pt^II₂Cu^II₂Zn^II)_n coordination polymers, depending on the counter anions. These compounds increased heterogeneous electrocatalytic activities for water oxidation in proportion to the number of vacant coordination sites at thiolato dicopper(II) cores.

中文翻译：

铜（ii）中心与硫醇基供体的配位几何形状可控制非均相催化水氧化†

用Cu ²⁺处理青霉氨基铂（II）金属配体得到S桥连的Pt ^II₂ Cu ^II_2配合物，该配合物与Zn ²⁺反应生成1D和3D（Pt ^II₂ Cu ^II₂ Zn ^II）_n配位聚合物，取决于抗衡阴离子。这些化合物与巯基双铜（II）核上的空位配位点数目成比例地增加了对水氧化的非均相电催化活性。

更新日期：2018-09-03

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