Fullerene has a definite 0D closed‐cage molecular structure composed of merely sp²‐hybridized carbon atoms, enabling it to serve as an important building block that is useful for constructing supramolecular assemblies and micro/nanofunctional materials. Conversely, graphene has a 2D layered structure, possessing an exceptionally large specific surface area and high carrier mobility. Likewise, other emerging graphene‐analogous 2D nanomaterials, such as graphitic carbon nitride (g‐C₃N₄), transition‐metal dichalcogenides (TMDs), hexagonal boron nitride (h‐BN), and black phosphorus (BP), show unique electronic, physical, and chemical properties, which, however, exist only in the form of a monolayer and are typically anisotropic, limiting their applications. Upon hybridization with fullerenes, noncovalently or covalently, the physical/chemical properties of 2D nanomaterials can be tailored and, in most cases, improved, significantly extending their functionalities and applications. Here, an exhaustive review of all types of hybrids of fullerenes and 2D nanomaterials, such as graphene, g‐C₃N₄, TMDs, h‐BN, and BP, including their preparations, structures, properties, and applications, is presented. Finally, the prospects of fullerene‐2D nanomaterial hybrids, especially the opportunity of creating unknown functional materials by means of hybridization, are envisioned.

中文翻译：

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富勒烯和二维纳米材料的混合物

^{富勒烯具有仅由sp 2}杂化碳原子组成的明确的0D闭笼分子结构，使其能够作为构建超分子组装体和微/纳米功能材料的重要构件。相反，石墨烯具有二维层状结构，具有异常大的比表面积和高载流子迁移率。同样，其他新兴的类石墨烯二维纳米材料，如石墨碳氮化物（g-C ₃ N ₄）、过渡金属二硫属化物（TMD）、六方氮化硼（h-BN）和黑磷（BP），也显示出独特的性能。然而，它们的电子、物理和化学性质仅以单层形式存在，并且通常是各向异性的，限制了它们的应用。与富勒烯非共价或共价杂化后，二维纳米材料的物理/化学性质可以定制，并且在大多数情况下可以得到改善，从而显着扩展其功能和应用。本文对富勒烯和二维纳米材料的所有类型的杂化物（例如石墨烯、g-C ₃ N ₄、TMDs、h-BN 和 BP）进行了详尽的综述，包括它们的制备、结构、性能和应用。最后，展望了富勒烯-2D纳米材料杂化物的前景，特别是通过杂化创造未知功能材料的机会。