Basic mesoporous zeolite ETS-10 (ETS-10-M) with high surface area (366 m²·g⁻¹) and large mesopores volume (0.21 cm³·g⁻¹) is synthesized by templated with an organosilan surfactant. After loading of Ni species and calcination, the obtained Ni/ETS-10-M as a bi-functional catalyst shows high activity and good product selectivity in the fluorination of N-aryl amides with N-fluorobenzenesulfonimide (NFSI). The Ni²⁺ species in Ni/ETS-10-M facilitate the formation of fluorine radical from NFSI, and the basic sites in Ni/ETS-10-M favour N-aryl amide transformation into corresponding carbon-radical, and reacted with fluorine radical to form the desired product. Ni/ETS-10-M catalyst exhibits good catalytic activity even it reused seven times.

通过以有机硅表面活性剂为模板，合成具有高表面积（366 m ² ·g ^-1）和大中孔体积（0.21 cm ³ ·g ^-1）的基本介孔沸石ETS-10（ETS-10-M）。负载镍物种并煅烧后，作为双功能催化剂的所得Ni / ETS-10-M在用N-氟代苯磺酰亚胺（NFSI）氟化N-芳基酰胺时显示出高活性和良好的产品选择性。Ni / ETS-10-M中的Ni ²⁺物种促进了NFSI形成氟自由基，Ni / ETS-10-M中的碱性位点有利于N-芳基酰胺转化为相应的碳自由基，并与氟自由基反应形成所需的产物。Ni / ETS-10-M催化剂即使重复使用7次也显示出良好的催化活性。