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Azobenzene-based solar thermal fuels: design, properties, and applications
Chemical Society Reviews ( IF 46.2 ) Pub Date : 2018-08-31 00:00:00 , DOI: 10.1039/c8cs00470f
Liqi Dong 1, 2, 3, 4 , Yiyu Feng 1, 2, 3, 4 , Ling Wang 1, 2, 3, 4 , Wei Feng 1, 2, 3, 4, 5
Affiliation  

Development of renewable energy technologies has been a significant area of research amongst scientists with the aim of attaining a sustainable world society. Solar thermal fuels that can capture, convert, store, and release solar energy in the form of heat through reversible photoisomerization of molecular photoswitches such as azobenzene derivatives are currently in the limelight of research. Herein, we provide a state-of-the-art account on the recent advancements in solar thermal fuels based on azobenzene photoswitches. We begin with an overview on the importance of azobenzene-based solar thermal fuels and their fundamentals. Then, we highlight the recent advances in diverse azobenzene materials for solar thermal fuels such as pure azobenzene derivatives, nanocarbon-templated azobenzene, and polymer-templated azobenzene. The basic design concepts of these advanced solar energy storage materials are discussed, and their promising applications are highlighted. We then introduce the recent endeavors in the molecular design of azobenzene derivatives toward efficient solar thermal fuels, and conclude with new perspectives on the future scope, opportunities and challenges. It is expected that continuous pioneering research involving scientists and engineers from diverse technological backgrounds could trigger the rapid advancement of this important interdisciplinary field, which embraces chemistry, physics, engineering, nanoscience, nanotechnology, materials science, polymer science, etc.

中文翻译:

基于偶氮苯的太阳能热燃料:设计,性能和应用

可再生能源技术的发展一直是科学家们研究的重要领域,目的是建立一个可持续的世界社会。通过分子光开关(如偶氮苯衍生物)的可逆光异构化,可以热能形式捕获,转化,储存和释放太阳能的太阳能燃料目前正在研究中。在此,我们提供有关基于偶氮苯光电开关的太阳能热燃料的最新进展的最新说明。我们首先概述基于偶氮苯的太阳能热燃料的重要性及其基本原理。然后,我们重点介绍了用于太阳能热燃料的各种偶氮苯材料的最新进展,例如纯偶氮苯衍生物,纳米碳模板的偶氮苯和聚合物模板的偶氮苯。讨论了这些先进的太阳能存储材料的基本设计概念,并突出了它们的有前途的应用。然后,我们介绍了在偶氮苯衍生物的分子设计中针对高效太阳能热燃料的最新努力,并以新的观点总结了未来的范围,机遇和挑战。预计,来自不同技术背景的科学家和工程师的不断开创性研究可能会触发这一重要的跨学科领域的快速发展,该领域涵盖化学,物理学,工程学,纳米科学,纳米技术,材料科学,聚合物科学,然后,我们介绍了在偶氮苯衍生物的分子设计中针对高效太阳能热燃料的最新努力,并以新的观点总结了未来的范围,机遇和挑战。预计,来自不同技术背景的科学家和工程师的不断开创性研究可能会触发这一重要的跨学科领域的快速发展,该领域涵盖化学,物理学,工程学,纳米科学,纳米技术,材料科学,聚合物科学,然后,我们介绍了在偶氮苯衍生物的分子设计中针对高效太阳能热燃料的最新努力,并以新的观点总结了未来的范围,机遇和挑战。预计,来自不同技术背景的科学家和工程师的不断开创性研究可能会触发这一重要的跨学科领域的快速发展,该领域涵盖化学,物理学,工程学,纳米科学,纳米技术,材料科学,聚合物科学,ETC。
更新日期:2018-08-31
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