当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Reductive activation of neptunyl and plutonyl oxo species with a hydroxypyridinone chelating ligand†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-08-30 00:00:00 , DOI: 10.1039/c8cc05626a
Korey P. Carter 1, 2, 3, 4 , Jiwen Jian 1, 2, 3, 4 , Mikaela M. Pyrch 4, 5, 6, 7 , Tori Z. Forbes 4, 5, 6, 7 , Teresa M. Eaton 1, 2, 3, 4 , Rebecca J. Abergel 1, 2, 3, 4, 8 , Wibe A. de Jong 2, 3, 4, 9 , John K. Gibson 1, 2, 3, 4
Affiliation  

Oxo group activation with reduction of neptunyl(VI) and plutonyl(VI) to tetravalent hydroxo species by the hydroxypyridinone siderophore derivative 3,4,3-LI-(1,2-HOPO) was investigated in the gas-phase via electrospray ionization mass spectrometry, in solution via Raman spectroscopy, and computationally via density functional theory. Dissociation of the gas-phase tetravalent complexes resulted in actinide–hydroxo bond cleavage.

中文翻译:

用羟基吡啶酮螯合配体还原激活海ept基和普通基氧代物质

在气相中,通过电喷雾电离质量研究了羟基吡啶酮酮铁基衍生物3,4,3-LI-(1,2-HOPO)活化的羰基活化反应,将庚基(VI)和and基(VI)还原为四价羟基。通过拉曼光谱法在溶液中进行光谱分析,并通过密度泛函理论进行计算。气相四价络合物的解离导致act系元素-羟基键裂解。
更新日期:2018-08-30
down
wechat
bug