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Star Atoms
The Journal of Physical Chemistry A ( IF 2.7 ) Pub Date : 2018-08-30 00:00:00 , DOI: 10.1021/acs.jpca.8b07358
Reinhold Blümel 1
Affiliation  

We define star atoms as dressed quantum star graphs with Coulomb potentials on their edges. Focusing on star-lithium (star-Li), we study its classical and quantum mechanics. We find that, classically, star-Li is completely chaotic. Quantum mechanically, we identify an energy regime in which star-Li shows Wigner statistics, a hallmark of quantum chaos. Our results are relevant for identifying energy regimes and conditions under which quantum chaos may be identified in lithium and other multiply excited many-electron atoms.

中文翻译:

星原子

我们将恒星原子定义为在其边缘具有库仑势的整齐的量子恒星图。重点研究星锂(star-Li),研究其经典和量子力学。我们发现,从传统上讲,李星是完全混乱的。在量子力学上,我们确定了一种能量状态,其中恒星Li显示了Wigner统计数据,这是量子混沌的标志。我们的结果与确定在锂和其他多激发多电子原子中可能识别出量子混沌的能态和条件有关。
更新日期:2018-08-30
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