Mesoporous materials have been proved to be meritorious for energy-related applications by virtue of their high surface areas and tunable porosities. Their interactions with guest species give rise to abundant accessible active sites, leading to easy mass/charge transfer. Recently, phosphorus-based mesoporous materials have attracted immense interest as a promising electrode/catalyst material for clean and renewable energy technologies, owing to their architectural superiority and intrinsic electrochemical activity. In particular, metal phosphates, phosphonates, and phosphides have demonstrated versatile electrocatalytic activity. Herein, we summarize the current state-of-the-art synthetic strategies of mesoporous metal phosphates, phosphonates, and phosphides for energy storage and conversion applications. Perspectives on the existing challenges in synthesis and application performance and opportunities for future material design are put forward.

介孔材料因其较高的表面积和可调节的孔隙率而被证明在能源相关应用方面具有优异的表现。它们与来宾物种的相互作用产生了大量可利用的活性位点，从而导致质量/电荷转移变得容易。近来，磷基介孔材料由于其结构上的优越性和固有的电化学活性而作为一种有望用于清洁和可再生能源技术的电极/催化剂材料引起了极大的兴趣。特别是，金属磷酸盐，膦酸盐和磷化物已证明具有多种电催化活性。在此，我们总结了介孔金属磷酸盐，膦酸盐和磷化物用于能量存储和转换应用的当前最先进的合成策略。