Catalysis inside the Hexameric Resorcinarene Capsule,Accounts of Chemical Research

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Catalysis inside the Hexameric Resorcinarene Capsule
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-08-28 00:00:00 , DOI: 10.1021/acs.accounts.8b00320
Qi Zhang ₁ , Lorenzo Catti ₁ , Konrad Tiefenbacher _{1,

2}

Affiliation

In this Account, we outline our investigation into the supramolecular resorcinarene capsule as a catalyst. Molecular capsules not only are of interest due to the similarities of their binding pockets with those of natural enzymes but also feature potential advantages for catalysis. Due to the restricted internal volume of the binding pockets, substrate selectivities are commonly observed. Substrates that are encapsulated more efficiently will be converted selectively in the presence of less suitable substrates. This size selectivity cannot be obtained in a regular solution experiment. In addition, because of the distinct chemical environment inside the capsule, different product selectivities may be observed. Furthermore, the encapsulation of reactive catalysts inside confined environments may improve catalyst compatibility for multicatalyst tandem reactions.

中文翻译：

六聚间苯二甲烯胶囊中的催化作用

在此帐户中，我们概述了对超分子间苯二甲烯胶囊作为催化剂的研究。分子胶囊不仅因其结合口袋与天然酶的相似之处而备受关注，而且具有催化的潜在优势。由于结合袋的内部体积有限，通常观察到底物选择性。在不太合适的基板存在下，被更有效地封装的基板将被选择性地转换。在常规溶液实验中无法获得这种尺寸选择性。此外，由于胶囊内部的化学环境不同，因此可以观察到不同的产品选择性。此外，

更新日期：2018-08-28

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