New self-assembling peptide nanotubes of large diameter using δ-amino acids†,Chemical Science

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New self-assembling peptide nanotubes of large diameter using δ-amino acids†
Chemical Science ( IF 7.6 ) Pub Date : 2018-08-27 00:00:00 , DOI: 10.1039/c8sc02276c
Alejandro Lamas ₁ , Arcadio Guerra ₁ , Manuel Amorín ₁ , Juan R Granja ₁

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Here we show that 4-aminocyclohexanecarboxylic acid is a rigid stretcher building block for the preparation of cyclic peptides that self-assemble to form peptide nanotubes with large diameter and hydrophobic pores. The hydrophobic properties of the resulting nanotubes provided by the two methylene groups per δ-residue allow the encapsulation of C₆₀ moieties forming a new type of bionanopeapod structure.

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