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Materials Functionalization with Multicomponent Reactions: State of the Art
ACS Combinatorial Science Pub Date : 2018-08-14 00:00:00 , DOI: 10.1021/acscombsci.8b00072
Ronak Afshari 1 , Ahmad Shaabani 1
Affiliation  

The emergence of neoteric synthetic routes for materials functionalization is an interesting phenomenon in materials chemistry. In particular, the union of materials chemistry with multicomponent reactions (MCRs) opens a new avenue leading to the realm of highly innovative functionalized architectures with unique features. MCRs have recently been recognized as considerable part of the synthetic chemist’s toolbox due to their great efficiency, inherent molecular diversity, atom and pot economy along with operational simplicity. Also, MCRs can improve E-factor and mass intensity as important green chemistry metrics. By rational tuning of the materials, as well as the MCRs, wide ranges of functionalized materials can be produced with tailorable properties that can play important roles in the plethora of applications. To date, there has not reported any exclusive review of a materials functionalization with MCRs. This critical review highlights the state-of-the-art on the one-pot functionalization of carbonaceous and siliceous materials, polysaccharides, proteins, enzymes, synthetic polymers, etc., via diverse kind of MCRs like Ugi, Passerini, Petasis, Khabachnik–Fields, Biginelli, and MALI reactions through covalent or noncovalent manners. Besides the complementary discussion of synthetic routes, superior properties and detailed applicability of each functionalized material in modern technologies are discussed. Our outlook also emphasizes future strategies for this unprecedented area and their use as materials for industrial implementation. With no doubt, MCRs-functionalization of materials bridges the gap between materials science domain and applied chemistry.

中文翻译:

具有多组分反应的材料功能化:最新技术

用于材料功能化的新型合成路线的出现是材料化学中一个有趣的现象。特别是,材料化学与多组分反应(MCR)的结合开辟了一条通往具有独特功能的高度创新的功能化体系结构领域的新途径。由于它们的高效率,固有的分子多样性,原子和罐的经济性以及操作的简便性,MCR最近被公认为是合成化学家工具箱的重要组成部分。同样,MCR可以改善E因子和质量强度,将其作为重要的绿色化学指标。通过对材料以及MCR进行合理的调整,可以生产具有可定制特性的各种功能化材料,这些特性可以在众多应用中发挥重要作用。迄今为止,尚无关于使用MCR进行材料功能化的独家报道。这篇重要的评论着重介绍了通过多种MCR(例如Ugi,Passerini,Petasis,Khabachnik–)对碳质和硅质材料,多糖,蛋白质,酶,合成聚合物等进行一锅功能化的最新技术。通过共价或非共价方式进行Fields,Biginelli和MALI反应。除了对合成路线的补充讨论之外,还讨论了每种功能化材料在现代技术中的优越性能和详细适用性。我们的前景还强调了这一空前领域的未来战略,并将其用作工业实施的材料。毫无疑问,材料的MCR功能化弥合了材料科学领域与应用化学之间的鸿沟。
更新日期:2018-08-14
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