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Cover Feature: Tuning the Electronic Properties and Acid‐Response Behavior of N‐Heteroacene‐Based π‐Conjugated Liquids by Changing the Number of π‐Conjugated Substituents (Chem. Asian J. 18/2018)
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2018-08-23 , DOI: 10.1002/asia.201800999
Yuika Sato 1 , Yuichiro Mutoh 2 , Daisuke Matsukuma 3 , Makoto Nakagawa 4 , Takeshi Kawai 4 , Kyosuke Isoda 1
Affiliation  

Two room‐temperature fluorescent π‐conjugated liquids based on a N‐heteroacene framework were designed and prepared with one or two thiophene rings. These liquid materials can be utilized as inks to be coated on substrates and displayed different electronic properties and rheology behavior; for example, fluorescent colors were light blue and blue, respectively. Moreover, dissolving various acids substances in these liquids gave rise to different fluorescent colors. Furthermore, when acids with lower pKa values were dissloved in these liquids, a phase transition occurred to a self‐organized liquid‐crystalline phase. More information can be found in the Full Paper by Kyosuke Isoda et al. on page 2619 in Issue 18, 2018 (DOI: 10.1002/asia.201800631).
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中文翻译:

封面功能:通过改变π共轭取代基的数量来调整基于N杂茂并苯的π共轭液体的电子性质和酸响应行为(Chem。Asian J. 18/2018)

设计并制备了两种基于N-杂并六苯构架的室温荧光π共轭液体,它们带有一个或两个噻吩环。这些液体材料可以用作要涂布在基材上的油墨,并显示出不同的电子性能和流变性。例如,荧光色分别是浅蓝色和蓝色。而且,将各种酸物质溶解在这些液体中会产生不同的荧光色。此外,当在这些液体中降低具有较低p K a值的酸时,会发生向自组织液晶相的相变。可以在Isoda Kyosuke等人的论文全文中找到更多信息。就在第18期,2018页2619(:10.1002 / asia.201800631 DOI)。
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更新日期:2018-08-23
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