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Thioester functional polymers
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-08-21 00:00:00 , DOI: 10.1039/c8py00872h Suzan Aksakal 1, 2, 3, 4, 5 , Resat Aksakal 1, 2, 3, 4, 5 , C. Remzi Becer 1, 2, 3, 4, 5
Polymer Chemistry ( IF 4.1 ) Pub Date : 2018-08-21 00:00:00 , DOI: 10.1039/c8py00872h Suzan Aksakal 1, 2, 3, 4, 5 , Resat Aksakal 1, 2, 3, 4, 5 , C. Remzi Becer 1, 2, 3, 4, 5
Affiliation
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Inspired by the uniqueness and ubiquity of thioesters in nature, much attention has been paid to thioester functionalized materials, yielding applications ranging from responsive polymers to bioconjugates and (bio)degradable polymers. This review focuses on various applications of thioesters in polymer science, covering the synthesis and polymerisation of thioester containing monomers, thioester generation via polymerization processes or the presence of thioesters in chain ends, such as initiators or chain transfer agents. Examples of post-polymerization modifications with various compounds (e.g. thiols, azides, amines and cysteine containing peptides) to enable modification via pathways such as ligation, amidation or exchange reactions are also presented.
中文翻译：
硫酯功能聚合物
受自然界中硫酯的独特性和普遍性的启发，人们对硫酯功能化材料给予了极大关注，其应用范围从响应性聚合物到生物共轭物和（生物）可降解聚合物。这篇综述集中于硫酯在聚合物科学中的各种应用，涵盖了含硫酯单体的合成和聚合，通过聚合过程生成硫酯或链端存在硫酯（例如引发剂或链转移剂）。还提供了使用各种化合物（例如，巯基，叠氮化物，胺和半胱氨酸的肽）进行聚合后修饰以通过诸如连接，酰胺化或交换反应等途径进行修饰的实例。
更新日期：2018-08-21
中文翻译：
硫酯功能聚合物
受自然界中硫酯的独特性和普遍性的启发，人们对硫酯功能化材料给予了极大关注，其应用范围从响应性聚合物到生物共轭物和（生物）可降解聚合物。这篇综述集中于硫酯在聚合物科学中的各种应用，涵盖了含硫酯单体的合成和聚合，通过聚合过程生成硫酯或链端存在硫酯（例如引发剂或链转移剂）。还提供了使用各种化合物（例如，巯基，叠氮化物，胺和半胱氨酸的肽）进行聚合后修饰以通过诸如连接，酰胺化或交换反应等途径进行修饰的实例。
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