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Synthesis of pumice-TiO2 nanoflakes for sonocatalytic degradation of famotidine
Journal of Cleaner Production ( IF 9.7 ) Pub Date : 2018-08-21 , DOI: 10.1016/j.jclepro.2018.08.165
Tannaz Sadeghi Rad , Alireza Khataee , Berkant Kayan , Dimitrios Kalderis , Sema Akay

Pumice-TiO2 was synthesized through simple sol-gel method. The successful synthesis of the catalyst was verified by SEM, EDS, XRF, FT-IR and BET techniques. Then, a sonocatalytic process was performed to degrade famotidine in the presence of the synthesized catalyst and under ultrasonic irradiation. The removal efficiency of the sonocatalytic process with pumice‒TiO2, TiO2, pumice and sonolysis within 70 min was 71.1%, 33.9%, 31.1% and 8.9%, respectively. The main operational parameters which were examined in this study were catalyst dosage, pH, famotidine concentration and ultrasonic power which were optimized as 1.5 g/L, 5, 20 mg/L and 150 W, respectively. Moreover, the addition of radical scavengers (EDTA, Na2SO4 and 1, 4–benzoquinone) and enhancers (H2O2 and K2S2O8) which can affect the removal efficiency were investigated. Diverse degradation by-products were identified using GC‒MS analysis. Eventually, the reusability tests confirmed that the synthesized pumice‒TiO2 catalyst had significant stability after 5 consecutive runs.



中文翻译:

浮石-TiO 2纳米片的合成用于声催化法莫替丁的降解

通过简单的溶胶-凝胶法合成了浮石-TiO 2。通过SEM,EDS,XRF,FT-IR和BET技术验证了催化剂的成功合成。然后,在合成催化剂存在下并在超声辐射下,进行声催化过程以降解法莫替丁。浮石‒ TiO 2,TiO 2,浮石和声分解在70分钟内对声催化过程的去除率分别为71.1%,33.9%,31​​.1%和8.9%。在这项研究中检查的主要操作参数是催化剂剂量,pH,法莫替丁浓度和超声功率,分别优化为1.5 g / L,5、20 mg / L和150W。此外,添加了自由基清除剂(EDTA,Na 2 SO 4和1,4-苯醌)和增强剂(H 2 O 2和K 2 S 2 O 8)会影响去除效率。使用GC‒MS分析鉴定了各种降解副产物。最终,可重复使用性测试证实了合成的浮石TiO 2催化剂在连续运行5次后具有显着的稳定性。

更新日期:2018-08-21
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