In this work, we described a facile synthesis of porous carbon (PCH₂O₂) using microwave-assisted pyrolysis and hydrogen peroxide as a chemical activator, almond shell was used as a raw source. The synthesized sample (PCH₂O₂) was used as a highly efficient adsorbent for ultrasound adsorption of antibiotic sulfamethoxazole (SMZ). The PC-H₂O₂ was characterized using X-Ray photoelectron spectroscopy, Brunauer–Emmett–Teller surface area (BET), X-ray Diffraction (XRD), X-Ray Scanning Electron Microscopy (SEM), Raman Spectroscopy, Fourier transform infrared (FTIR), Fluorescence X and Boehm titration. The PC-H₂O₂ was found to have a high surface area of 1274 m²/g, which provide a large number of active sites for SMZ molecules. The pseudo-second-order model described the ultrasound-assisted adsorption kinetics data. The isotherms were accurately described by the Langmuir model with a monolayer adsorption capacity of 344.8 mg/g. The adsorption mechanism was proposed based on FTIR analysis before and after ultrasound-assisted adsorption. The reusability of PC-H₂O₂ loaded SMZ was investigated and Response Surface Methodology was used to optimize the removal efficiency of SMZ.

在这项工作中，我们描述了使用微波辅助热解和过氧化氢作为化学活化剂，以杏仁壳为原料，轻松合成多孔碳（PC H ₂ O ₂）。合成的样品（PC H ₂ O ₂）被用作高效超声吸附抗生素磺胺甲恶唑（SMZ）的吸附剂。使用X射线光电子能谱，Brunauer-Emmett-Teller表面积（BET），X射线衍射（XRD），X射线扫描电子显微镜（SEM），拉曼光谱，傅里叶变换对PC-H ₂ O ₂进行表征红外（FTIR），荧光X和Boehm滴定。PC-H ₂ O ₂据发现，其具有1274 m ² / g的高表面积，其为SMZ分子提供了大量的活性位点。拟二级模型描述了超声辅助的吸附动力学数据。等温线由Langmuir模型精确描述，单层吸附容量为344.8 mg / g。基于FTIR分析提出了超声辅助吸附前后的吸附机理。研究了PC-H ₂ O ₂负载SMZ的可重用性，并使用响应表面方法优化了SMZ的去除效率。