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Organo silica nanosheets with gemini surfactants for rapid adsorption of ibuprofen from aqueous solutions
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-08-18 , DOI: 10.1016/j.jtice.2018.07.038
Hao Zeng , Manglai Gao , Tao Shen , Fan Ding

Gemini surfactants with different alkyl chain lengths, [C16H33N+ (CH3)2CH2]2•2Br (G16-2-16), [C12H25N+ (CH3)2CH2]2•2Br (G12-2-12), and [C8H17N+ (CH3)2CH2]2•2Br (G8-2-8), were applied to modify Silica nanosheets (SiNSs). FT-IR, XRD, TG, SEM, TEM, BET and Zeta potentials were carried out to study the surface and structure of the resultant organo silica nanosheets (organo-SiNSs). The loading amounts of G16-2-16, G12-2-12, and G8-2-8 were 0.23, 0.14, and 0.09 mmol for 1 g SiNSs, respectively, suggesting the increased length of the alkyl chain promoted the modification process. Organo-SiNSs exhibited rapid adsorption property (within 5 min) and high adsorption capacity (64.19 mg g−1) toward ibuprofen (IBP) at such a low surfactant concentration (0.42 mmol for 1 g SiNSs), and can be regenerated at least for 3 cycles. Furthermore, the longer the alkyl chain, the more IBP removed, the adsorption capacities of three organo-SiNSs decreased in the order G16-2-16-SiNSs (64.19 mg g−1) > G12-2-12-SiNSs (40.14 mg g−1) > G8-2-8-SiNSs (4.84 mg g−1). Moreover, electrostatic interaction as well as the partition effect plays an important role in the adsorption. Based on the fast adsorption and cost-effective feature, organo-SiNSs were further proved to be outstanding adsorbents for specific organics removal.



中文翻译:

含有双子表面活性剂的有机硅纳米片,可从水溶液中快速吸附布洛芬

双子表面活性剂具有不同的烷基链长,[C 16 H ^ 33 Ñ +(CH 32 CH 2 ] 2 •2BR -(G 16-2-16),[C 12 H ^ 25 Ñ +(CH 32 CH 2 ] 2 •2BR -(G 12-2-12),和[C 8 H ^ 17 ñ +(CH 32 CH 2 ] 2 •2BR -(G8-2-8)被用于改性二氧化硅纳米片(SiNSs)。进行了FT-IR,XRD,TG,SEM,TEM,BET和Zeta电位研究了所得有机硅纳米片(organic-SiNSs)的表面和结构。1 g SiNS的G 16-2-16,G 12-2-12和G 8-2-8的负载量分别为0.23、0.14和0.09 mmol,这表明增加的烷基链长度促进了SNS的负载。修改过程。有机SiNSs具有快速吸附性能(5分钟内)和高吸附容量(64.19 mg g -1))在如此低的表面活性剂浓度下(1 g SiNSs为0.42 mmol)向布洛芬(IBP)迁移,并且至少可以再生3个循环。此外,烷基链越长,除去的IBP越多,三种有机-SiNS的吸附能力按G 16-2-16 -SiNSs(64.19 mg g -1)> G 12-2-12 -SiNSs( 40.14 mg g -1)> G 8-2-8 -SiNSs(4.84 mg g -1)。而且,静电相互作用以及分配效应在吸附中起重要作用。基于快速吸附和具有成本效益的特点,有机-SiNS被进一步证明是去除特定有机物的杰出吸附剂。

更新日期:2018-08-18
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