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Synthesis of ordered mesoporous MgAl composite oxide-supported potassium catalysts for biodiesel production
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-08-16 , DOI: 10.1016/j.catcom.2018.08.014
Dahai Pan , Tonglian Liu , Feng Yu , Shuwei Chen , Xiaoliang Yan , Xiufeng Shi , Binbin Fan , Ruifeng Li

Ordered mesoporous MgAl composite oxide-supported K catalysts (xK/OMMA) were prepared and used for soybean oil transesterification with methanol. The prepared xK/OMMA demonstrated a much higher soybean oil conversion (up to 97.0%) along with a 99.8% selectivity to fatty acid methyl ester and a desirable reusability, compared with K-based catalysts prepared with the same K loading and using ordered mesoporous alumina or mesoporous MgAl mixed oxide as support. The superior catalytic performance of xK/OMMA is associated with the excellent structural and surface properties of support OMMA, thus benefiting the generation of catalytically active sites and their highly homogenous dispersion.



中文翻译:

用于生物柴油生产的有序介孔Mg Al复合氧化物负载的钾催化剂的合成

制备了有序介孔的Mg Al复合氧化物负载的K催化剂(x K / OMMA),并将其用于大豆油与甲醇的酯交换反应。与以相同的K负载和使用有序K制备的K基催化剂相比,所制备的x K / OMMA具有更高的豆油转化率(高达97.0%)以及对脂肪酸甲酯的99.8%的选择性和理想的可重复使用性。介孔氧化铝或介孔Mg Al混合氧化物作为载体。x K / OMMA的出色催化性能与载体OMMA的出色结构和表面性能有关,因此有利于催化活性位点的生成及其高度均一的分散。

更新日期:2018-08-16
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