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The effect of SiC addition on photoluminescence of YAG:Ce phosphor for white LED
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2018-08-16 , DOI: 10.1016/j.jeurceramsoc.2018.08.018
Dusan Bucevac , Vladimir Krstic

An effective way of improving photoluminescence (PL) of YAG:Ce by addition of small amount of SiC and sintering in air was described. The breakdown of SiC during sintering process in air was employed to provide the presence of SiO2 and CO both of which are known to be beneficial in enhancing the PL of YAG:Ce phosphor. SiC in the form of a fine powder was added to YAG:Ce powder and sintered to densities of >99% of theoretical density. The highest luminescence was measured in sample containing 0.08 wt% SiC. The effect of the formed SiO2 and CO was discussed and their contribution to the emission intensity was assessed. The enhancement of PL intensity is attributed to the formation of vacancies, both on Y sub-lattice and on oxygen sub-lattice and their ability to release the electrons for subsequent reduction of Ce4+ to Ce3+ which plays a role of luminescence activator.



中文翻译:

SiC添加对YAG:Ce荧光粉用于白光LED的光致发光的影响

描述了一种通过添加少量SiC并在空气中烧结来改善YAG:Ce的光致发光(PL)的有效方法。在空气中的烧结过程中,SiC的分解被用来提供SiO 2和CO的存在,这两种已知都有助于提高YAG:Ce荧光粉的PL。将细粉形式的SiC添加到YAG:Ce粉末中,并烧结至> 99%理论密度的密度。在包含0.08 wt%SiC的样品中测量到最高的发光度。形成的SiO 2的作用讨论了CO,并评估了它们对排放强度的贡献。PL强度的增强归因于Y亚晶格和氧亚晶格上空位的形成,以及它们释放电子以随后将Ce 4+还原为Ce 3+的能力,后者起着发光激活剂的作用。

更新日期:2018-08-16
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