Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure–Property Relationships and Applications,Chemical Reviews

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Rise of Conjugated Poly-ynes and Poly(Metalla-ynes): From Design Through Synthesis to Structure–Property Relationships and Applications
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-08-16 00:00:00 , DOI: 10.1021/acs.chemrev.8b00022
Ashanul Haque ₁ , Rayya A. Al-Balushi ₁ , Idris Juma Al-Busaidi ₁ , Muhammad S. Khan ₁ , Paul R. Raithby ₂

Affiliation

Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their intriguing and tunable chemical and photophysical properties. This review highlights fascinating advances made in the field of conjugated organic poly-ynes and poly(metalla-ynes) incorporating group 4–11 metals. This includes several important aspects of conjugated poly-ynes viz. synthetic protocols, bonding, electronic structure, nature of luminescence, structure–property relationships, diverse applications, and concluding remarks. Furthermore, we delineated the future directions and challenges in this particular area of research.

中文翻译：

共轭聚乙炔和聚金属乙炔的兴起：从设计到合成再到结构-性能关系及其应用

共轭聚炔和聚金属炔构成了重要的一类新材料，在各种科学领域都有潜在的应用前景。导致这些材料多样化使用的关键因素是其有趣的，可调节的化学和光物理性质。这篇综述着重介绍了在共轭有机聚炔和结合了4-11族金属的聚（金属炔）领域中取得的引人入胜的进步。这包括共轭聚炔的几个重要方面。合成协议，绑定，电子结构，发光性质，结构与属性之间的关系，各种应用程序以及结束语。此外，我们描述了该特定研究领域的未来方向和挑战。

更新日期：2018-08-16

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