Recent Advances in Radical‐Enabled Bicyclization and Annulation/1,n‐Bifunctionalization Reactions,Chemistry - An Asian Journal

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Recent Advances in Radical‐Enabled Bicyclization and Annulation/1,n‐Bifunctionalization Reactions
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2018-09-19 , DOI: 10.1002/asia.201801119
Min-Hua Huang _{1,

2} , Wen-Juan Hao ₁ , Bo Jiang ₁

Affiliation

Over the past few years, the development of new radical reactions has gained considerable momentum. Most such radical transformations heavily depend on the in situ generation of reactive radical species, initiated by oxidants, metal salts, visible‐light photocatalysis, or electrocatalysis. In this context, numerous radical‐enabled bicyclization and annulation/1,n‐bifunctionalization reactions have been developed, thereby providing efficient synthetic strategies for the assembly of functionalized cyclic rings that contain both heterocyclic and isocyclic skeletons. In this Focus Review, we highlight recent progress in this rapidly growing area by presenting a series of catalytic oxidative reactions, along with their reaction mechanisms and applications.

中文翻译：

自由基促成双环化和环化/ 1，n-双官能化反应的最新进展

在过去的几年中，新的激进反应的发展获得了可观的势头。大多数此类自由基转化在很大程度上取决于由氧化剂，金属盐，可见光光催化或电催化引发的反应性自由基物种的原位生成。在这种情况下，已经开发了许多自由基使能的双环化和环化/ 1，n-双官能化反应，从而为组装包含杂环和杂环骨架的官能化环提供了有效的合成策略。在本焦点回顾中，我们通过介绍一系列催化氧化反应及其反应机理和应用，重点介绍了这一快速增长领域中的最新进展。

更新日期：2018-09-19

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