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Catalytic oxidation of benzene to phenol with hydrogen peroxide over Fe-terpyridine complexes supported on a cation exchange resin
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-08-13 , DOI: 10.1016/j.catcom.2018.08.011
Syuhei Yamaguchi , Kohei Miyamoto , Hidenori Yahiro

The catalytic activity of [Fe(terpy)2]2+ complexes supported on the cation exchange resins, ([Fe(terpy)2]2+@resin), was investigated for the oxidation of benzene with H2O2 to yield phenol. The catalytic activity of an [Fe(terpy)2]2+@Nafion catalyst for the oxidation of benzene with H2O2 was observed to be five times more than that in case of the [Fe(terpy)2]2+@resin catalysts. Among the [Fe(terpy)2]2+@resin catalysts that were investigated in this study, the [Fe(terpy)2]2+@Nafion catalyst exhibits the highest durability against H2O2 because the other resins were dissolved or dispersed in the reaction solvent. Nafion was found to be the best candidate among the polymer supports for loading the Fe complex active to perform the oxidation of a substrate with H2O2.



中文翻译:

阳离子交换树脂上负载的Fe-吡啶吡啶配合物用过氧化氢将苯催化氧化为苯酚

研究了负载在阳离子交换树脂上的[Fe(terpy )2 ] 2+络合物([Fe(terpy)2 ] 2+ @resin)的催化活性,以H 2 O 2氧化苯生成苯酚。观察到[Fe(terpy )2 ] 2+ @Nafion催化剂对苯被H 2 O 2氧化的催化活性是[Fe(terpy )2 ] 2+ @的五倍。树脂催化剂。在本研究中研究的[Fe(terpy )2 ] 2+树脂催化剂中,[Fe(terpy)2 ] 2+ Nafion催化剂对H 2 O 2的耐久性最高,因为其他树脂溶解或分散在反应溶剂中。发现Nafion是用于负载Fe络合物活性物以执行H 2 O 2氧化底物的聚合物载体中的最佳候选物。

更新日期:2018-08-13
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