Bisphosphine phenol and phenolate complexes of Mn(i): manganese(i) catalyzed Tishchenko reaction†,Dalton Transactions

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Bisphosphine phenol and phenolate complexes of Mn(i): manganese(i) catalyzed Tishchenko reaction†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-08-14 00:00:00 , DOI: 10.1039/c8dt02933d
Karthika J. Kadassery _{1,

2,

3,

4,

5} , Samantha N. MacMillan _{5,

6,

7,

8} , David C. Lacy _{1,

2,

3,

4,

5}

Affiliation

We synthesized new organomanganese complexes using the phenolic “pincer” type ligand H-POP. The coordination chemistry of H-POP with Mn(I) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.

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