Efficient conversion of CO₂ into fuels and chemicals with solar energy would be promising, but also faces great challenge. In this context, we describe the photoreductive functionalization of CO₂ to construct new C−C, C−N, and C−O bonds through the respective Pd‐catalyzed Suzuki carbonylation, aminocarbonylation, and alkoxycarbonylation of aryl iodides with CO in situ generated through the photoreduction of CO₂. This protocol opens up an alternative avenue for CO₂ utilization by harnessing solar energy.

中文翻译：

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集成的光催化还原二氧化碳和随后的羰基化反应：光催化还原功能化的二氧化碳

利用太阳能将CO ₂有效地转化为燃料和化学物质将是有希望的，但同时也面临着巨大的挑战。在这种情况下，我们描述了CO ₂的光还原功能化，通过相应的Pd催化的芳基碘化物的Pd催化的Suzuki羰基化，氨基羰基化和烷氧基羰基化，通过原位生成CO来构建新的C C，C N和C O键。 CO ₂的光还原。该协议通过利用太阳能为CO ₂利用开辟了一条替代途径。