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In situ regeneration of commercial NH3-SCR catalysts with high-temperature water vapor
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-08-13 , DOI: 10.1016/j.catcom.2018.08.009
Yao Shi , Pei Zhang , Tuotuo Fang , Erhao Gao , Fujuan Xi , Tianyu Shou , Mengna Tao , Siming Wu , Matthew T. Bernards , Yi He , Hua Pan

The performance of a commercial NH3-SCR catalyst used for 20,000 h in a 660 MW coal fired power plant was evaluated after treated in situ with water vapor at 300–350 °C for 336 h. The conversion of NOx reached 91.4% after this water treatment. The recovery of catalytic activity is mainly due to the removal of potassium, arsenic and sulfate-containing deposits from the catalyst surface, as well as the increase of surface active oxygen species and specific surface area. These results indicate that commercial NH3-SCR catalysts are deactivated by the deposition of water-soluble substances and which can be in situ regenerated cost-effectively with high-temperature water vapor treatment.



中文翻译:

高温水蒸气对工业NH 3 -SCR催化剂的原位再生

在660 MW的燃煤电厂中,使用NH 3 -SCR商用催化剂20,000小时后,在300-350°C的水蒸气中原位处理336 h后,对其性能进行了评估。在该水处理之后,NO x的转化率达到91.4%。催化活性的恢复主要归因于从催化剂表面去除了钾,砷和硫酸盐的沉积物,以及表面活性氧种类和比表面积的增加。这些结果表明,商业NH 3 -SCR催化剂通过水溶性物质的沉积而失活,并且可以通过高温水蒸气处理以成本有效的方式原位再生。

更新日期:2018-08-13
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