Visible‐light‐enabled photocatalytic carbotrifluoro‐methylations of allylic alcohols and sodium triflinate were explored through 1,2‐migration of an aryl group, affording an efficient method for synthesis of β‐trifluoromethyl‐α‐substituted carbonyl compounds under mild reaction conditions. This catalyst system is well tolerant of various synthetically useful functional groups.

中文翻译：

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可见光诱导的光氧化还原催化通过1,2-芳基迁移实现烯丙醇的碳三氟甲基化

通过芳基的1,2-迁移探索了烯丙醇和三氟甲磺酸钠的可见光光催化碳三氟甲基化，为在温和的反应条件下合成β-三氟甲基-α-取代的羰基化合物提供了一种有效的方法。该催化剂体系对各种合成有用的官能团具有良好的耐受性。