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Tf2O‐Promoted Trifluoromethythiolation of Various Arenes Using NaSO2CF3
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-09-04 , DOI: 10.1002/adsc.201800702
Jie Liu 1 , Xiaochun Zhao 1 , Lvqi Jiang 1 , Wenbin Yi 1
Affiliation  

A sulfonic anhydride‐promoted direct trifluoromethylthiolation using NaSO2CF3 has been developed. The simple and practical strategy enabled the direct introduction of SCF3 moiety into unexplored arene scaffolds under reductant‐ and metal‐free condition at room temperature.

中文翻译:

使用NaSO2CF3的Tf2O促进的各种芳烃的三氟甲基硫醇化

已开发出使用NaSO 2 CF 3的磺酸酐促进的直接三氟甲基硫醇化反应。简单而实用的策略可以在室温下在无还原剂和无金属的条件下将SCF 3部分直接引入未开发的芳烃支架中。
更新日期:2018-09-04
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