New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol,Organic Process Research & Development

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New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol
Organic Process Research & Development ( IF 3.1 ) Pub Date : 2018-08-09 00:00:00 , DOI: 10.1021/acs.oprd.8b00156
Babak Karimi _{1,

2} , Mina Ghahremani ₁ , Rosaria Ciriminna ₃ , Mario Pagliaro ₃

Affiliation

We report the first catalytically active and stable sol–gel electrode functionalized with the TEMPO moiety for the highly selective oxidation of alcohols with an electric current only. The method shows broad applicability to different substrates, opening the route to the widespread adoption of this eminently clean technology by the fine chemical and pharmaceutical industries.

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