In this study, the metal organic framework MOF [Zn(BDC)(DMF)] crystal was synthesized via ultrasonic irradiation and solvothermal method. The synthesized MOF [Zn(BDC)(DMF)] crystal was characterized by PXRD, FTIR, FESEM-EDX, TGA, UV-DRS and BET. The catalytic activity of MOF [Zn(BDC)(DMF)] was investigated by 4-nitrophenol (4-NP) degradation under direct sunlight irradiation. The influence of various degradation parameters such as initial 4-NP concentration, dosage, pH and H₂O₂ concentration were investigated. The results indicated that the synthesized MOF [Zn(BDC)(DMF)] exhibited strong photocatalytic activity in the presence of NaBH₄ under sunlight irradiation and the reduction of 4-NP to 4-aminophenol (4-AP) completed within 10 min. The study provides the synthesized MOF [Zn(BDC)(DMF)] crystal can be used as a high performance catalyst for the treatment of dyes in wastewater.

本研究通过超声辐射和溶剂热法合成了金属有机骨架MOF [Zn（BDC）（DMF）]晶体。通过PXRD，FTIR，FESEM-EDX，TGA，UV-DRS和BET对合成的MOF [Zn（BDC）（DMF）]晶体进行了表征。通过在阳光直射下4-硝基苯酚（4-NP）的降解研究了MOF [Zn（BDC）（DMF）]的催化活性。研究了各种降解参数的影响，如初始4-NP浓度，剂量，pH和H ₂ O ₂浓度。结果表明，合成的MOF [Zn（BDC）（DMF）]在NaBH ₄存在下表现出较强的光催化活性。在阳光照射下，在10分钟内将4-NP还原为4-氨基苯酚（4-AP）。该研究提供了合成的MOF [Zn（BDC）（DMF）]晶体可用作高性能催化剂，用于处理废水中的染料。