A simple and selective colorimetric method for the detection of perilous peroxide explosives was developed using the peroxidase mimetic activity of silver nanoparticles/flake-like zinc metal-organic framework nanocomposite (Ag@ZnMOF). The synthesis of Ag@ZnMOF contained the formation of silver nanoparticles (AgNPs) inside the fine pores of Zn metal-organic framework (ZnMOF). High reactive AgNPs as well as great surface area of MOFs provided a synergetic and high improved catalytic activity for the composite which was studied as a peroxidase mimic in hydrogen peroxide (H₂O₂)-based oxidations. The achieved system was used for detection of Triacetone triperoxide (TATP) as one of the most hazardous peroxide explosives. TATP was decomposed in an acidic condition to generate H₂O₂, which was then applied to oxidize 3,3′,5,5′-tetramethylbenzidine (TMB) in the presence of the Ag@ZnMOF as a catalyst. This reaction led to the production of well-known blue colored charge transfer complex (oxTMB), which was recognized by the colorimetric technique. A linear relationship was obtained between the absorption intensity of the produced blue solution and the TATP concentration in the range of 0.4-15 mg L^-1, with a detection limit of 0.1 mg L^-1. A portable test kit was prepared using the same reagents for TATP measurement in real samples.

利用银纳米颗粒/片状锌金属有机骨架纳米复合材料（Ag @ ZnMOF）的过氧化物酶模拟活性，开发了一种简单，选择性的比色法检测危险的过氧化物炸药。Ag @ ZnMOF的合成包含在锌金属有机骨架（ZnMOF）的细孔内形成银纳米颗粒（AgNPs）。高反应性的AgNPs和较大的MOF表面积为复合材料提供了协同作用和高的催化活性，这是作为过氧化物酶模拟物在基于过氧化氢（H ₂ O ₂）的氧化中研究的。所获得的系统用于检测三丙酮三过氧化物（TATP），这是最危险的过氧化物炸药之一。TATP在酸性条件下分解产生H ₂然后在Ag @ ZnMOF作为催化剂存在下，将O ₂应用于氧化3,3'，5,5'-四甲基联苯胺（TMB）。该反应导致了众所周知的蓝色电荷转移复合物（oxTMB）的生产，该复合物已通过比色技术得到了认可。所产生的蓝色溶液的吸收强度与TATP浓度在0.4-15 mg L ^-1范围内，检测限为0.1 mg L ^-1之间具有线性关系。使用相同的试剂制备了便携式测试试剂盒，用于实际样品中的TATP测量。