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High-sulfur capacity and regenerable Zn-based sorbents derived from layered double hydroxide for hot coal gas desulfurization
Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2018-08-06 , DOI: 10.1016/j.jhazmat.2018.08.015
Mengmeng Wu , Bingwei Chang , Teik-Thye Lim , Wen-Da Oh , Junxi Lei , Jie Mi

The Zn-Al mixed metal oxide (ZnAl-MMO) with a plate-like structure was derived from Zn-Al layered double hydroxide. The ZnAl-MMO with a Zn/Al molar ratio of 3:1 exhibits superior absorption ability for H2S in a simulated coal gas at 600 ℃ due to the special structure of the ZnAl-MMO. Besides ZnS, elemental sulfur is also produced during the desulfurization process. The deactivation model could well simulate the absorption behavior of H2S. The sulfidation reaction over the sorbent shows large initial reaction rate constants (1110–5390 m3 min-1 kg-1) and low activation energy (29.5 kJ mol−1). The regeneration rate of the used sorbent can reach 99.8% under the optimum conditions. The regenerated sorbents still show high sulfur capacity (ca. 30%), implying its great application potential for industrial-scale desulfurization of the hot coal gas.



中文翻译:

层状双氢氧化物的高硫容量和可再生锌基吸附剂,用于热煤气脱硫

具有板状结构的Zn-Al混合金属氧化物(ZnAl-MMO)由Zn-Al层状双氢氧化物衍生而来。Zn / Al摩尔比为3:1的ZnAl-MMO由于ZnAl-MMO的特殊结构,在600℃的模拟煤气中对H 2 S表现出优异的吸收能力。除ZnS外,脱硫过程中还会产生单质硫。失活模型可以很好地模拟H 2 S的吸收行为。吸附剂上的硫化反应显示出较大的初始反应速率常数(1110-5390 m 3  min -1 kg -1)和较低的活化能(29.5 kJ mol -1)。在最佳条件下,所用吸附剂的再生率可以达到99.8%。再生的吸附剂仍显示出高硫容量(30%),这表明其在工业规模的热煤气脱硫方面具有巨大的应用潜力。

更新日期:2018-08-06
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