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Simultaneous absorption of carbon dioxide and nitrogen dioxide from simulated flue gas stream using gas-liquid membrane contacting system
International Journal of Greenhouse Gas Control ( IF 4.6 ) Pub Date : 2018-08-03 , DOI: 10.1016/j.ijggc.2018.07.026
Jalil Ghobadi , David Ramirez , Shooka Khoramfar , Robert Jerman , Michele Crane , Kenneth Hobbs

Membrane gas contactors are a promising alternative to conventional post-combustion carbon capture technologies. However, residuals of the other acid gas compounds can exist in the flue gas streams emitted from industrial facilities, having a notable impact on the absorption performance of the membrane system. Simultaneous removal of CO2 and NO2 from a simulated flue gas stream was carried out in a polytetrafluoroethylene (PTFE) hollow fiber gas-liquid membrane contacting (GLMC) system using different scrubbing solutions. A series of experiments were conducted to study the effects of operating conditions such as gas and liquid cross flow velocities, concentration of feed gas, absorbent nature and concentration, and long-term performance of the GLMC system on the removal efficiencies as well as mass transfer rates of CO2 and NO2. Experimental results indicated that simultaneous absorption of CO2 and NO2 were enhanced with increasing the liquid-phase cross flow velocity, decreasing gas-phase cross flow velocity, and using chemical stripping absorbents. Moreover, it was shown the sodium hydroxide to be a superior absorbent as compared to alkanolamine solutions for the co-capture of CO2 and NO2 species. It was observed that low concentrations of NO2 in the feed gas had a minimal impact on the decarbonization of GLMC system. The durability of the membrane system was also evaluated by running the simultaneous gas removal experiments over a 24-h period. The consistency of the absorption efficiency results confirmed the potential of using PTFE membrane system for the simultaneous absorption of CO2 and NO2 gases.



中文翻译:

气液膜接触系统同时从模拟烟道气中吸收二氧化碳和二氧化氮

膜式气体接触器是常规燃烧后碳捕集技术的有希望的替代品。但是,其他酸性气体化合物的残留物可能存在于从工业设施排放的烟气流中,这对膜系统的吸收性能有显着影响。同时去除CO 2和NO 2使用不同的洗涤溶液,在模拟的烟气流中,从聚四氟乙烯(PTFE)中空纤维气液膜接触(GLMC)系统中进行萃取。进行了一系列实验来研究诸如气体和液体的横流速度,进料气体的浓度,吸收剂的性质和浓度以及GLMC系统的长期性能等操作条件对去除效率和传质的影响。 CO 2和NO 2的比率。实验结果表明,CO 2和NO 2同时吸收通过增加液相错流速度,降低气相错流速度和使用化学汽提吸收剂,可以提高碳氢化合物的吸收率。而且,显示出与烷醇胺溶液相比,氢氧化钠是用于CO 2和NO 2物种的共同捕获的优良吸收剂。观察到进料气体中低浓度的NO 2对GLMC系统的脱碳影响最小。膜系统的耐用性还通过在24小时内进行同时的除气实验来评估。吸收效率结果的一致性证实了使用PTFE膜系统同时吸收CO 2和NO 2气体的潜力。

更新日期:2018-08-03
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