Catalytic Transfer Hydrogenation Using Biomass as Hydrogen Source,ChemSusChem

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Catalytic Transfer Hydrogenation Using Biomass as Hydrogen Source
ChemSusChem ( IF 7.5 ) Pub Date : 2018-08-22 , DOI: 10.1002/cssc.201801770
Srimanta Manna _{1,

2} , Andrey P. Antonchick _{1,

2,

3}

Affiliation

We developed an operationally simple method for the direct use of biomass‐derived chemical entities in a fundamentally important process, such as hydrogenation. Various carbohydrates, starch, and lignin were used for stereoselective hydrogenation. Employing a transition metal catalyst and a novel catalytic system, the reduction of alkynes, alkenes, and carbonyl groups with high yields was demonstrated. The regioselective hydrogenation to access different stereoisomers was established by simple variations in the reaction conditions. This work is based on an unprecedented catalytic system and represents a straightforward application of biomass as a reducing reagent in chemical reactions.

中文翻译：

以生物质为氢源的催化转移加氢

我们开发了一种操作简单的方法，可在基本重要的过程（例如加氢）中直接使用生物质衍生的化学实体。各种碳水化合物，淀粉和木质素用于立体选择性氢化。利用过渡金属催化剂和新颖的催化体系，证明了炔烃，烯烃和羰基的高产率还原。通过简单改变反应条件来建立区域选择性氢化以得到不同的立体异构体。这项工作基于前所未有的催化系统，代表了生物质作为还原剂在化学反应中的直接应用。

更新日期：2018-08-22

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