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Cocrystallization of Imide‐Fused Corannulene Derivatives and C60: Guest‐Induced Conformational Switching and 1:1 Segregated Packing
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2018-08-24 , DOI: 10.1002/asia.201801086
Ru-Qiang Lu 1 , Shuang Wu 1 , Yue-Hua Bao 1 , Lin-Lin Yang 1 , Hang Qu 1 , Mithu Saha 1 , Xiao-Ye Wang 2 , You-Zhen Zhuo 1 , Binbin Xu 3 , Jian Pei 4 , Hui Zhang 1 , Wengui Weng 1 , Xiao-Yu Cao 1
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A pair of interconvertible stereoisomers of imide‐fused corannulene derivatives was mixed with C60, which resulted in cocrystallization into a 1:1 segregated packing motif through concave–convex π–π interactions. Only one conformation was observed in the cocrystal owing to guest‐induced conformational switching. The 1D assemblies of the complex showed promising applications in organic electronics.

中文翻译:

酰亚胺融合的戊二烯衍生物和C60的共结晶:客体诱导的构象转换和1:1分离堆积

将一对酰亚胺融合的邻苯二酚衍生物的互变立体异构体与C 60混合,通过凹-凸π-π相互作用共结晶为1:1分离的堆积基序。由于客体诱导的构象转换,在共晶中仅观察到一种构象。该综合体的一维组件显示了在有机电子领域中的有希望的应用。
更新日期:2018-08-24
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