Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions,Dalton Transactions

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Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-07-26 00:00:00 , DOI: 10.1039/c8dt02572j
Yoshiaki Nishibayashi _{1,

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Affiliation

This paper describes our recent progress in catalytic nitrogen fixation using transition metal–dinitrogen complexes as catalysts. Our research group has recently developed novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and hydrazine using molybdenum–, iron–, cobalt– and vanadium–dinitrogen complexes under mild reaction conditions. The new findings presented in this paper may provide a new approach to the development of economical nitrogen fixation to replace the energy-consuming Haber–Bosch process.

中文翻译：

在温和的反应条件下使用过渡金属-二氮配合物开发催化固氮方法

本文介绍了我们在使用过渡金属-二氮配合物作为催化剂进行催化固氮方面的最新进展。我们的研究小组最近开发了新颖的反应系统，用于在温和的反应条件下使用钼，铁，钴和钒的钒二氮配合物将分子中的二氮催化转化为氨和肼。本文介绍的新发现可能为开发经济的固氮技术提供新的方法，以取代耗能的Haber-Bosch工艺。

更新日期：2018-07-26

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