Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands†,Dalton Transactions

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Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-07-25 00:00:00 , DOI: 10.1039/c8dt02739k
Yoshiya Sekiguchi _{1,

2,

3,

4,

5} , Fanqiang Meng _{1,

2,

3,

4,

5} , Hiromasa Tanaka _{5,

6,

7,

8} , Aya Eizawa _{1,

2,

3,

4,

5} , Kazuya Arashiba _{1,

2,

3,

4,

5} , Kazunari Nakajima _{1,

2,

3,

4,

5} , Kazunari Yoshizawa _{5,

6,

7,

8} , Yoshiaki Nishibayashi _{1,

2,

3,

4,

5}

Affiliation

Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.

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