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Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-07-25 00:00:00 , DOI: 10.1039/c8dt02739k
Yoshiya Sekiguchi 1, 2, 3, 4, 5 , Fanqiang Meng 1, 2, 3, 4, 5 , Hiromasa Tanaka 5, 6, 7, 8 , Aya Eizawa 1, 2, 3, 4, 5 , Kazuya Arashiba 1, 2, 3, 4, 5 , Kazunari Nakajima 1, 2, 3, 4, 5 , Kazunari Yoshizawa 5, 6, 7, 8 , Yoshiaki Nishibayashi 1, 2, 3, 4, 5
Affiliation  

Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.

中文翻译:

带有阴离子吡咯基PNP型钳形配体的钛和锆二氮配合物的合成和反应性

制备带有阴离子吡咯基PNP型钳型配体的二氮桥双钛和二锆配合物,并通过X射线分析对其进行表征。研究了它们在温和的反应条件下将氮气还原为氨和肼的催化活性。
更新日期:2018-07-25
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