Reaction of β‐(2‐aminophenyl)‐α,β‐Ynones with Tosyl Isocyanate: Experimental and Computational Investigations,Advanced Synthesis & Catalysis

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Reaction of β‐(2‐aminophenyl)‐α,β‐Ynones with Tosyl Isocyanate: Experimental and Computational Investigations
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-08-14 , DOI: 10.1002/adsc.201800733
Navnath D. Rode ₁ , Massimiliano Aschi ₁ , Marco Chiarini ₂ , Luana Del Vecchio ₁ , Fabio Marinelli ₁ , Antonio Arcadi ₁

Affiliation

A practical metal‐free approach to the synthesis of 2‐aroyl‐N‐tosyl‐1H‐indole‐3 carboxamides through an unprecedented sequential 5‐endo‐dig cycloamination /carboxamidation reaction of β‐(2‐aminophenyl)‐α,β‐ynones with the tosyl isocyanate is described. A computational model gives a plausible rationale for the unexpected results.

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