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A flexible 3D [email protected]@MoS2 hybrid foam anode for high-performance lithium-ion battery
Chemical Engineering Journal ( IF 13.3 ) Pub Date : 2018-07-21 , DOI: 10.1016/j.cej.2018.07.139
Jing Ren , Rui-Peng Ren , Yong-Kang Lv

A three-dimensional (3D) flexible hybrid foam composed of graphene [email protected] nanotubes decorated with MoS2 nanoparticles is synthesized for flexible anode applications in lithium-ion battery. The inner layer of graphene foam (GF), serving as a 3D skeleton of the hybrid foam, enlarges the electrode/electrolyte contact, shortens the diffusion distance of Li+ ions and provides enough internal void space to accommodate the large volume change of MoS2 nanoparticles. The middle carbon nanotubes (CNT) layer wrapped on the graphene foam is more conductive to facilitate electron/ion transport within the hybrid foam and can further enhance the flexibility of the hybrid foam. The outer layer of active MoS2 nanoparticles can provide high specific capacity. Owing to these advantages, the flexible [email protected]@MoS2 electrodes delivers a specific capacity of 935 mAh g−1 at a current density of 0.1 A g−1, high reversible capacity of 606 mAh g−1 after 200 cycles at 0.2 A g−1.



中文翻译:

灵活的3D [受电子邮件保护] @MoS 2混合泡沫阳极,用于高性能锂离子电池

合成了由装饰有MoS 2纳米粒子的石墨烯(受电子邮件保护的)纳米管组成的三维(3D)柔性杂化泡沫,用于锂离子电池中的柔性阳极应用。石墨烯泡沫(GF)的内层用作混合泡沫的3D骨架,可扩大电极/电解质的接触,缩短Li +离子的扩散距离,并提供足够的内部空隙空间以适应MoS 2的大体积变化纳米粒子。包裹在石墨烯泡沫上的中间碳纳米管(CNT)层更具导电性,以促进杂化泡沫内的电子/离子传输,并可以进一步增强杂化泡沫的柔韧性。活性MoS 2的外层纳米粒子可以提供高比容量。由于这些优点,灵活的[电子邮件保护] @MoS 2电极在0.1 A g -1的电流密度下可提供935 mAh g -1的比容量,在0.2的200次循环后具有606 mAh g -1的高可逆容量A g -1

更新日期:2018-07-21
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