N‐Alkylation of Fulleropyrrolidines by Aminomethylation Reaction of Ketones/Arylboronic Acids,Advanced Synthesis & Catalysis

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N‐Alkylation of Fulleropyrrolidines by Aminomethylation Reaction of Ketones/Arylboronic Acids
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-08-03 , DOI: 10.1002/adsc.201800633
Cheng Huang ₁ , Gang Huang ₁ , Hui-Juan Wang ₂ , Fa-Bao Li ₁ , Zhen Wang ₁ , Yongshun Huang ₁ , Li Liu ₁ , Chao-Yang Liu ₂

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N‐alkylation of fulleropyrrolidines in the presence of polyformaldehyde and p‐toluenesulfonic acid was systematically investigated. With the addition of ketones/arylboronic acids, a series of novel N‐alkyl fulleropyrrolidines were formed. Nevertheless, in the absence of ketones/arylboronic acids, scarce N‐methyl fulleropyrrolidines were obtained with the aid of benzyl alcohol. Possible reaction pathways for the formation of N‐alkyl fulleropyrrolidines were proposed to elucidate the above reaction process.

中文翻译：

酮/芳基硼酸的氨甲基化反应对全吡咯烷进行N-烷基化

系统地研究了在聚甲醛和对甲苯磺酸的存在下，全吡咯烷的N-烷基化反应。通过添加酮/芳基硼酸，形成了一系列新型的N-烷基全吡咯烷。然而，在没有酮/芳基硼酸的情况下，借助于苄醇获得了稀有的N-甲基全吡咯烷。为了阐明上述反应过程，提出了形成N-烷基全吡咯烷酮的可能反应途径。

更新日期：2018-08-03

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