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Nitrogen doped carbon coating of PbLi2Ti6O14 as high electrochemical performance anode towards long-life lithium storage
Electrochimica Acta ( IF 5.5 ) Pub Date : 2018-07-17 , DOI: 10.1016/j.electacta.2018.07.117
Haoxiang Yu , Yafen Zhang , Xing Cheng , Haojie Zhu , Runtian Zheng , Tingting Liu , Jundong Zhang , Miao Shui , Jie Shu

To fulfill the requirement for large-scale energy-storage systems, lithium ions batteries have been attracted great attentions. It is necessary to develop the anode material with high rate capability, long cycling life and outstanding safety. Here, N-doped carbon been successfully synthesized and estimated as an anode material for lithium ions batteries. PbLi2Ti6O14 is isostructural with SrLi2Ti6O14. After nitrogen-doped carbon coating, PbLi2Ti6O14@NC delivers a high capacity of 143.2 mAh g−1 at a current density of 100 mA g−1 and remains 104.8 mAh g−1 even at 700 mA g−1. In addition, PbLi2Ti6O14@NC also possesses excellent cyclic stability. The reversible capacity of PbLi2Ti6O14@NC can keep at 99.7 mAh g−1 after 1500 cycles. Such results are also proved by CV tests and EIS measurements. Meanwhile, the lithium storage mechanism of PbLi2Ti6O14@NC is investigated by an in situ XRD technique. It indicates that PbLi2Ti6O14@NC has a stable structural host. These aforementioned results suggest that PbLi2Ti6O14@NC has great potential working as an anode material for lithium ions batteries.



中文翻译:

PbLi 2 Ti 6 O 14的氮掺杂碳涂层作为高电化学性能的阳极,可实现长寿命的锂存储

为了满足大规模储能系统的需求,锂离子电池引起了极大的关注。有必要开发具有高倍率能力,长循环寿命和出色安全性的负极材料。在此,已成功合成并估计了N掺杂的碳,并将其作为锂离子电池的负极材料。PbLi 2 Ti 6 O 14与SrLi 2 Ti 6 O 14是同构的。氮掺杂碳涂层后,PbLi 2 Ti 6 O 14 @NC在100 mA g -1的电流密度下可提供143.2 mAh g -1的高容量,并保持104.8 mAh g-1即使在700 mA g -1时也是如此。另外,PbLi 2 Ti 6 O 14 @NC也具有优异的循环稳定性。1500次循环后,PbLi 2 Ti 6 O 14 @NC的可逆容量可保持在99.7 mAh g -1。CV测试和EIS测量也证明了这样的结果。同时,通过原位XRD技术研究了PbLi 2 Ti 6 O 14 @NC的锂存储机理。这表明PbLi 2 Ti 6 O 14 @NC具有稳定的结构主体。上述结果表明,PbLi 2Ti 6 O 14 @NC具有很大的潜力,可作为锂离子电池的负极材料。

更新日期:2018-07-17
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