Single-molecule magnet behaviour in a dysprosium-triradical complex†,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Single-molecule magnet behaviour in a dysprosium-triradical complex†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-07-17 00:00:00 , DOI: 10.1039/c8cc04739a
Zhao-Xin Xiao _{1,

2,

3,

4,

5} , Hao Miao _{1,

2,

3,

4,

5} , Dong Shao _{1,

2,

3,

4,

5} , Hai-Yan Wei _{5,

6,

7,

8,

9} , Yi-Quan Zhang _{8,

9,

10,

11,

12} , Xin-Yi Wang _{1,

2,

3,

4,

5}

Affiliation

The first triradical bridged binuclear penta-spin single-molecule magnet, [Dy₂(hfac)₆(BTR)], based on a nitronyl nitroxide triradical was synthesized and characterized. Theoretical calculations revealed Dy-radical antiferromagnetic coupling and radical–radical ferromagnetic coupling. The SMM behavior is found to originate from the exchange states, rather than the isolated Dy³⁺ center.

中文翻译：