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Diastereoselective self-assembly of bisheptahelicene on Cu(111)†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-07-17 00:00:00 , DOI: 10.1039/c8cc04160a
Anaïs Mairena 1, 2, 3 , Manfred Parschau 1, 2, 3 , Johannes Seibel 1, 2, 3 , Martin Wienke 4, 5, 6, 7 , Daniel Rentsch 1, 2, 3 , Andreas Terfort 7, 8, 9, 10 , Karl-Heinz Ernst 1, 2, 3, 11, 12
Affiliation  

Stereochemical effects during two-dimensional crystallization of bisheptahelicene diastereomers on a Cu(111) surface have been studied with scanning tunnelling microscopy. The (M,M)- and (P,P)-enantiomers crystallize into a monolayer racemate lattice, whereas the (M,P)-diastereomers aggregate into their own monolayer phase.

中文翻译:

比色庚烯在Cu(111)上的非对映选择性自组装

用扫描隧道显微镜研究了比塞庚基烯非对映异构体在Cu(111)表面上的二维结晶过程中的立体化学效应。(MM)-和(PP)-对映体结晶成单层外消旋体晶格,而(MP)-非对映体聚集成它们自己的单层相。
更新日期:2018-07-17
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