Diastereoselective self-assembly of bisheptahelicene on Cu(111)†,Chemical Communications

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Diastereoselective self-assembly of bisheptahelicene on Cu(111)†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-07-17 00:00:00 , DOI: 10.1039/c8cc04160a
Anaïs Mairena _{1,

2,

3} , Manfred Parschau _{1,

2,

3} , Johannes Seibel _{1,

2,

3} , Martin Wienke _{4,

5,

6,

7} , Daniel Rentsch _{1,

2,

3} , Andreas Terfort _{7,

8,

9,

10} , Karl-Heinz Ernst _{1,

2,

3,

11,

12}

Affiliation

Stereochemical effects during two-dimensional crystallization of bisheptahelicene diastereomers on a Cu(111) surface have been studied with scanning tunnelling microscopy. The (M,M)- and (P,P)-enantiomers crystallize into a monolayer racemate lattice, whereas the (M,P)-diastereomers aggregate into their own monolayer phase.

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