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Metal‐Organic Layers Catalyze Photoreactions without Pore Size and Diffusion Limitations
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-09-27 , DOI: 10.1002/chem.201803635 Ruoyu Xu 1 , Tasha Drake 1 , Guangxu Lan 1 , Wenbin Lin 1
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-09-27 , DOI: 10.1002/chem.201803635 Ruoyu Xu 1 , Tasha Drake 1 , Guangxu Lan 1 , Wenbin Lin 1
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Metal‐organic frameworks (MOFs) have emerged as promising single‐site solid catalysts for organic reactions. However, MOF catalysts suffer from pore size limitation and slow diffusion, which are detrimental for photoreactions. Metal‐organic layers (MOLs) have unique ultrathin 2D monolayer structures and overcome pore size and diffusion limitations. Here, the synthesis of photoactive Zr‐RuBPY MOL based on Zr‐oxo clusters and [Ru(bpy)3]2+‐containing linkers is reported as well as its application in photocatalytic [2+2] cyclizations of enones and Meerwein addition reactions between aryl diazonium salts, styrenes, and nitriles.
中文翻译：
金属有机层可催化光反应，而无孔尺寸和扩散限制
金属有机框架（MOF）已成为有前途的有机反应单中心固体催化剂。但是，MOF催化剂受孔径限制和扩散缓慢的影响，这不利于光反应。金属有机层（MOL）具有独特的超薄二维单层结构，并克服了孔径和扩散限制。在这里，报道了基于Zr-oxo簇和含[Ru（bpy）3 ] 2+的连接基的光活性Zr-RuBPY MOL的合成及其在烯酮的光催化[2 + 2]环化反应和Meerwein加成反应中的应用。介于芳基重氮盐，苯乙烯和腈之间。
更新日期：2018-09-27
中文翻译：
金属有机层可催化光反应，而无孔尺寸和扩散限制
金属有机框架（MOF）已成为有前途的有机反应单中心固体催化剂。但是，MOF催化剂受孔径限制和扩散缓慢的影响，这不利于光反应。金属有机层（MOL）具有独特的超薄二维单层结构，并克服了孔径和扩散限制。在这里，报道了基于Zr-oxo簇和含[Ru（bpy）3 ] 2+的连接基的光活性Zr-RuBPY MOL的合成及其在烯酮的光催化[2 + 2]环化反应和Meerwein加成反应中的应用。介于芳基重氮盐，苯乙烯和腈之间。
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