The first separation of enantiomers in capillary electrophoresis (CE) counts slightly longer than three decades. Fast development of the practice and theory of chiral CE occurred in the past 30 years and today one can consider this technology to have a solid and mature theoretical background. The goal of the present review is not only to summarize the history and contemporary theory of enantioseparations by using CE but also to present the authors personal view where shall we head to with this attractive technology not only from the viewpoint of separation of enantiomers but also for better understanding the mechanisms of non-covalent (enantioselective) interactions in chemistry, biology, medicine and related disciplines.

对映异构体在毛细管电泳（CE）中的首次分离计数要比三十年代稍长。在过去的30年中，手性CE的实践和理论迅速发展，今天人们可以认为该技术具有扎实而成熟的理论背景。本综述的目的不仅是通过使用CE总结对映异构体的历史和当代理论，而且还提出作者个人的观点，我们不仅应从对映体分离的角度出发，还应使用这种有吸引力的技术。更好地了解化学，生物学，医学和相关学科中非共价（对映选择性）相互作用的机制。